Templating effect of single-layer graphene supported by an insulating substrate on the molecular orientation of lead phthalocyanine

• K. Priya Madhuri,
• Abhay A. Sagade,
• Pralay K. Santra and
• Neena S. John

Beilstein J. Nanotechnol. 2020, 11, 814–820, doi:10.3762/bjnano.11.66

• Technology, Kattankulathur 603 203, Tamil Nadu, India 10.3762/bjnano.11.66 Abstract The influence of single-layer graphene on top of a SiO2/Si surface on the orientation of nonplanar lead phthalocyanine (PbPc) molecules is studied using two-dimensional grazing incidence X-ray diffraction. The studies

• specific device applications. Keywords: conducting atomic force microscopy (C-AFM); lead phthalocyanine (PbPc); molecular orientation; single-layer graphene; substrate effect; two-dimensional grazing incidence X-ray diffraction (2D-GIXRD); Introduction Organic semiconductors have been extensively used in

• –molecule interactions [1][2][3][4]. Nonplanar MPcs, such as lead phthalocyanine (PbPc), are particularly interesting in the field of photovoltaics due to their extraordinary near-infrared (NIR) absorption. The chemical structure of a PbPc molecule is given in Figure 1. The well-known polymorphs of